添付ファイルを追加するには、新しいMIMEパーツを作成し、それをメッセージに追加するだけです。
例:
// create a new Zend\Mail\Message object
$message = new Message;
// create a MimeMessage object that will hold the mail body and any attachments
$bodyPart = new MimeMessage;
// create the attachment
$attachment = new MimePart(fopen($pathToAttachment));
// or
$attachment = new MimePart($attachmentContent);
// set attachment content type
$attachment->type = 'image/png';
// create the mime part for the message body
// you can add one for text and one for html if needed
$bodyMessage = new MimePart($body);
$bodyMessage->type = 'text/html';
// add the message body and attachment(s) to the MimeMessage
$bodyPart->setParts(array($bodyMessage, $attachment));
$message->setEncoding('utf-8')
->setTo($email)
->setReplyTo($replyTo)
->setFrom($from)
->setSubject($subject)
->setBody($bodyPart); // set the body of the Mail to the MimeMessage with the mail content and attachment
この件に関する役立つドキュメントは次のとおりです。ZF2-Zend\Mail