実験データを使用した理論的分析のための次のコードがあります。曲線を当てはめ、S_u0 値を外挿して初期温度を決定しようとしています。
# Determination of laminar burning velocities from experimental data using constant volume pressure rise method.
import numpy as np
import openpyxl as xl
import matplotlib.pylab as plt
from lmfit import Model
plt.rc('font',family='Book Antiqua',size=12)
p_i=float(2.0) # Initial pressure
c=float(2.0265) # Constant
V_b=float(1.94e-3) # Volume of combustion bomb
k_u=float(1.3) # Specific heat ratio of unburnt mass
k_b=float(1.27) # Specific heat ratio of burnt mass
# Extracting experimental data from excel.
wb = xl.load_workbook("G:/Laminar Paper/Data/T0444CH1.xlsx")
ws = wb.active
# Calculation of initial voltage from experimental values.
num_cells=list(ws['B2':'B1500'])
V_initial=[]
for row in num_cells:
for cell in row:
V_initial.append(cell.value)
V_av=np.absolute(sum(V_initial)/len(V_initial)) # Average voltage
# Determining the final voltage from the experimental values.
num_cells=list(ws['B3':'B13252'])
V_final=[] # Experimental testing voltages
for row in num_cells:
for cell in row:
V_final.append(cell.value)
p=(V_final/np.floor(c))+(p_i-(V_av/np.floor(c))) # Combustion pressure
# The time elapse.
num_cells=list(ws['A3':'A13252'])
time=[]
for row in num_cells:
for cell in row:
time.append(cell.value)
# Curve fitting.
Func_1=np.polyfit(time, p, 15)
Func_2=np.poly1d(Func_1)
time_new=np.linspace(time[0], time[-1], 50) # New time values
p_new=Func_2(time_new) # New pressure values/filtered pressure
dp_dt=np.gradient(p_new,time_new) # Derivative of pressure wrt time
# Linear approximation method.
x_linear=(p_new-p_i)/(max(p_new)-p_i) # Burnt mass fraction
R_b=(pow(((V_b*3)/(4*np.pi)), 1.0/3))
S_u1=((1-(1-x_linear)*(p_i/p_new)**1/k_u)**-2/3)
S_u2=S_u1*((p_i/p_new)*1/k_u)
S_u3=S_u2*(1/(max(p_new)-p_i))*dp_dt
S_u=(R_b/3)*S_u3 # Linear approximation laminar flame speed
# Two-zone approach.
func_p=(k_b-1)/(k_u-1)+(((k_u-k_b)/(k_u-1))*(p_new/p_i)**((k_u-1)/k_u))
x_2zone=(p_new-p_i*func_p)/(max(p)-p_i*func_p) # Burnt mass fraction
S_uz1=((1-(1-x_2zone)*(p_i/p_new)**1/k_u)**-2/3)
S_uz2=S_uz1*((p_i/p_new)*1/k_u)
S_uz3=S_uz2*(1/(max(p_new)-p_i))*dp_dt
S_uz=(R_b/3)*S_uz3 # Two-zone laminar flame speed
# Model function.
def mod_m(n,su0=1,alpha=1):
return su0*(n)**alpha
# S_u and pressure ratio array data for fitting and calculating S_u0 and T_0.
n=np.array([1.78759326,1.91173221,2.05673713,2.22911249,2.4360555,2.68433232,2.97885016])
m=np.array([0.20791161,0.20332239,0.20206572,0.20260075,0.20292399,0.20115307,0.19601662])
# Fitting model.
model=Model(mod_m)
# Making a set of parameters (for 'su0' and 'alpha'):
params=model.make_params(s_u0=10)
# Setting min/max bounds on parameters:
params['alpha'].min=0.0
params['su0'].min=0.0
params['su0'].max=1e2
# Run the fit with Model.fit(Data_Array, Parameters, independent vars).
result=model.fit(m,params,n=n)
# Plotting.
plt.plot(n,result.best_fit,'b*-', label='Fit')
plt.plot(p_new/p_i,S_u,'k--',linewidth='2',label='Linear')
plt.plot(p_new/p_i,S_uz,'r-',label='Two-zone')
plt.xlabel('Pressure ratio $p/p_i$')
plt.ylabel('Laminar flame speed $(S_u)$ [m/s]')
plt.legend(loc='lower right')
plt.savefig('Laminar.png')
plt.show()
# Printing report with results and fitting statistics.
print(result.fit_report())
プロット後、図 1 を取得しましたが、図 2 のようなプロットを取得したいと考えています。どうすれば図 2 のような図を取得できますか。よろしくお願いします。
図1
図 2